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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
As such water percolates through calcium carbonate rock, the CaCO 3 dissolves according to one of the trends above. When that same water then emerges from the tap, in time it comes into equilibrium with CO 2 levels in the air by outgassing its excess CO 2. The calcium carbonate becomes less soluble as a result, and the excess precipitates as ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
Limestone forms when calcite or aragonite precipitate out of water containing dissolved calcium, which can take place through both biological and nonbiological processes. [41] The solubility of calcium carbonate (CaCO 3) is controlled largely by the amount of dissolved carbon dioxide (CO 2) in the water. This is summarized in the reaction:
The result: 1 liter of water can dissolve 1.34 × 10 −5 moles of AgCl at room temperature. Compared with other salts, AgCl is poorly soluble in water. For instance, table salt (NaCl) has a much higher K sp = 36 and is, therefore, more soluble. The following table gives an overview of solubility rules for various ionic compounds.
The exact value of the CCD depends on the solubility of calcium carbonate which is determined by temperature, pressure and the chemical composition of the water – in particular the amount of dissolved CO 2 in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures.
As the groundwater enters the cave, the excess carbon dioxide is released from the solution of the bicarbonate, causing the much less soluble calcium carbonate to be deposited. In the reverse process, dissolved carbon dioxide (CO 2) in rainwater (H 2 O) reacts with limestone calcium carbonate (CaCO 3) to form soluble calcium bicarbonate (Ca(HCO ...
However, there is an equilibrium between dissolved calcium bicarbonate and dissolved calcium carbonate as represented by the chemical equation Ca 2+ + 2 HCO − 3 ⇌ Ca 2+ + CO 2− 3 + CO 2 + H 2 O. Note that CO 2 is dissolved in the water. Carbon dioxide dissolved in water (aq) tends to equilibrate with carbon dioxide in the gaseous state (g ...