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Vaska's complex, trans-IrCl(CO)(PPh 3) 2, is also historically significant; it was used to establish the scope of oxidative addition reactions. This early work provided the insights that led to the flowering of the area of homogeneous catalysis. NiCl 2 (PPh 3) 2 is a tetrahedral (spin triplet) complex of Ni(II). In contrast PdCl 2 (PPh 3) 2 is ...