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The boron atom in BH 3 has 6 valence electrons. Consequently, it is a strong Lewis acid and reacts with any Lewis base ('L' in equation below) to form an adduct: [7] BH 3 + L → L—BH 3. in which the base donates its lone pair, forming a dative covalent bond. Such compounds are thermodynamically stable, but may be easily oxidised in air.
A borane is a compound with the formula BR x H y although examples include multi-boron derivatives. A large family of boron hydride clusters is also known. In addition to some applications in organic chemistry , the boranes have attracted much attention as they exhibit structures and bonding that differs strongly from the patterns seen in ...
The great variety of boranes show a huge covalent cluster chemistry, but the heavier group 13 hydrides do not. Despite their formulae, however, they tend to form polymers. Alane(aluminum trihydride) is a strong reducing agent with octahedrally coordinated aluminium atom
Boranes are chemical compounds of boron and hydrogen, with the generic formula of B x H y. These compounds do not occur in nature. Many of the boranes readily oxidise on contact with air, some violently. The parent member BH 3 is called borane, but it is known only in the gaseous state, and dimerises to form diborane, B 2 H 6. The larger ...
Boron hydride clusters are compounds with the formula B x H y or related anions, where x ≥ 3. Many such cluster compounds are known. Common examples are those with 5, 10, and 12 boron atoms. Although they have few practical applications, the borane hydride clusters exhibit structures and bonding that differs strongly from the patterns seen in ...
The C-B bond has low polarity (electronegativity 2.55 for carbon and 2.04 for boron). Alkyl boron compounds are in general stable, though easily oxidized. Boron often forms electron-deficient compounds without a full octet, such as the triorganoboranes. These compounds are strong electrophiles, but typically too sterically hindered to dimerize.
Ternary metal hydrides have the formula A x MH n, where A + is an alkali or alkaline earth metal cation, e.g. K + and Mg 2+. A celebrated example is K 2 ReH 9, a salt containing two K + ions and the ReH 9 2− anion. Other homoleptic metal hydrides include the anions in Mg 2 FeH 6 and Mg 2 NiH 4.
Decaborane, also called decaborane(14), is the inorganic compound with the chemical formula B 10 H 14. It is classified as a borane and more specifically a boron hydride cluster. This white crystalline compound is one of the principal boron hydride clusters, both as a reference structure and as a precursor to other boron hydrides.