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In thermodynamics, vapor quality is the mass fraction in a saturated mixture that is vapor; [1] in other words, saturated vapor has a "quality" of 100%, and saturated liquid has a "quality" of 0%. Vapor quality is an intensive property which can be used in conjunction with other independent intensive properties to specify the thermodynamic ...
This quality is defined as the fraction of the total mixture which is vapor, based on mass. [3] A fully saturated vapor has a quality of 100% while a saturated liquid has a quality of 0%. Quality can be estimated graphically as it is related to the specific volume, or how far horizontally across the dome the point exists.
The construction of a liquid vapor phase diagram assumes an ideal liquid solution obeying Raoult's law and an ideal gas mixture obeying Dalton's law of partial pressure. A tie line from the liquid to the gas at constant pressure would indicate the two compositions of the liquid and gas respectively. [14]
The vapor condenses on glass spurs (known as theoretical trays or theoretical plates) inside the column, and returns to the distilling flask, refluxing the rising distillate vapor. The hottest tray is at the bottom of the column and the coolest tray is at the top. At steady-state conditions, the vapor and liquid on each tray reach an equilibrium.
It has also been used for the same purpose in designing trayed fractionating columns, trayed absorption columns and other vapor–liquid-contacting columns. A vapor–liquid separator drum is a vertical vessel into which a liquid and vapor mixture (or a flashing liquid) is fed and wherein the liquid is separated by gravity, falls to the bottom ...
VLE of the mixture of chloroform and methanol plus NRTL fit and extrapolation to different pressures. The non-random two-liquid model [1] (abbreviated NRTL model) is an activity coefficient model introduced by Renon and Prausnitz in 1968 that correlates the activity coefficients of a compound with its mole fractions in the liquid phase concerned.
The Duhem–Margules equation, named for Pierre Duhem and Max Margules, is a thermodynamic statement of the relationship between the two components of a single liquid where the vapour mixture is regarded as an ideal gas:
An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. [1] The enthalpy of mixing is zero [2] as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes.