Search results
Results From The WOW.Com Content Network
Rhodium catalysts are used in some industrial processes, notably those involving carbon monoxide. In the Monsanto process, rhodium iodides catalyze the carbonylation of methanol to produce acetic acid. [43] This technology has been significantly displaced by the iridium-based Cativa process, which effects the same conversion but more efficiently.
Organorhodium chemistry is the chemistry of organometallic compounds containing a rhodium-carbon chemical bond, and the study of rhodium and rhodium compounds as catalysts in organic reactions. [ 1 ] Stable organorhodium compounds and transient organorhodium intermediates are used as catalyst such as in olefin hydroformylation , olefin ...
Wilkinson's catalyst (chloridotris(triphenylphosphine)rhodium(I)) is a coordination complex of rhodium with the formula [RhCl(PPh 3)], where 'Ph' denotes a phenyl group. It is a red-brown colored solid that is soluble in hydrocarbon solvents such as benzene, and more so in tetrahydrofuran or chlorinated solvents such as dichloromethane .
Rhodium-platinum oxide (Rh–Pt oxide), or Nishimura's catalyst, is an inorganic compound used as a hydrogenation catalyst. [2] Uses
Methods for the stereoselective synthesis of cyclopropanes from diazocarbonyl compounds and olefins have relied on either the use of pre-formed chiral rhodium catalysts or chiral auxiliaries on the diazocarbonyl compound. For example, Rh 2 [S-DOSP] 4 is a highly effective catalyst for the enantioselective cyclopropanation of alkenes. [9] (3)
Rhodium is used as a reduction catalyst, palladium is used as an oxidation catalyst, and platinum is used both for reduction and oxidation. Cerium, iron, manganese, and nickel are also used, although each has limitations. Nickel is not legal for use in the European Union because of its reaction with carbon monoxide into toxic nickel tetracarbonyl.
Rhodium(II) acetate is the coordination compound with the formula Rh 2 (AcO) 4, where AcO − is the acetate ion (CH 3 CO − 2). This dark green powder is slightly soluble in polar solvents, including water. It is used as a catalyst for cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex. [2]
Subsequent migratory insertion of the alkene into the rhodium-hydride bond can give two regioisomeric alkyl rhodium(III) boride complexes. Reductive elimination of the boronate ester regenerates the catalyst. Catalyst prepared and handled under anaerobic condition reverses the selectivity to favor the secondary boronate ester.