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If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will cause an excess of products, and the system will try to counteract this by increasing the reverse reaction and pushing the ...
Equilibrium chemistry is concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero.
Comfortable equilibrium, or the Clarinda Equilibrium refers to the psychological state of mental harmony and equanimity with the frequently opposing stresses and strains of complicated circumstances in tension. As situations unfold, there will be the tendency for the equilibrium to shift and adjust, yet for these different stable equilibria ...
In most simple microeconomic stories of supply and demand a static equilibrium is observed in a market; however, economic equilibrium can be also dynamic. Equilibrium may also be economy-wide or general, as opposed to the partial equilibrium of a single market. Equilibrium can change if there is a change in demand or supply conditions.
Thermodynamic equilibrium is a notion of thermodynamics with axiomatic status referring to an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls.
In a new bottle of soda, the concentration of carbon dioxide in the liquid phase has a particular value. If half of the liquid is poured out and the bottle is sealed, carbon dioxide will leave the liquid phase at an ever-decreasing rate, and the partial pressure of carbon dioxide in the gas phase will increase until equilibrium is reached.
The subgame perfect equilibrium in addition to the Nash equilibrium requires that the strategy also is a Nash equilibrium in every subgame of that game. This eliminates all non-credible threats , that is, strategies that contain non-rational moves in order to make the counter-player change their strategy.
For equilibria in solution use a medium of high ionic strength. In effect this redefines the standard state as referring to the medium. Activity coefficients in the standard state are, by definition, equal to 1. The value of an equilibrium constant determined in this manner is dependent on the ionic strength.