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Jannik Bjerrum (son of Niels Bjerrum) developed the first general method for the determination of stability constants of metal-ammine complexes in 1941. [1] The reasons why this occurred at such a late date, nearly 50 years after Alfred Werner had proposed the correct structures for coordination complexes, have been summarised by Beck and Nagypál. [2]
HSAB is an acronym for "hard and soft (Lewis) acids and bases".HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species.
Aluminium carbonate (Al 2 (CO 3) 3), is a carbonate of aluminium.It is not well characterized; one authority says that simple carbonates of aluminium are not known. [2] However related compounds are known, such as the basic sodium aluminium carbonate mineral dawsonite (NaAlCO 3 (OH) 2) and hydrated basic aluminium carbonate minerals scarbroite (Al 5 (CO 3)(OH) 13 •5(H 2 O)) and ...
Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula FeCO 3, that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations Fe 2+ and carbonate anions CO 2− 3. [5] The compound crystallizes in the same motif as calcium carbonate. In this ...
In April 2015 researchers at Stanford University claimed to have developed an aluminium-ion battery with a recharge time of about one minute (for an unspecified battery capacity). [7] Their cell provides about 2 volts, 4 volts if connected in a series of two cells. [7] [25] The prototype lasted over 7,500 charge-discharge cycles with no loss of ...
To a single metal ion, carbonate is observed to bind in both unidentate (κ 1-) and bidentate (κ 2-) fashions. [5] In the covalent bond classification method, κ 1-carbonate is anX ligand and κ 2-carbonate is an X 2 ligand. With two metals, the number of bonding modes increases because carbonate often serves as a bridging ligand.
Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".
The design battery energy density is 1300 Wh/kg (present) or 2000 Wh/kg (projected). The cost of battery system chosen to evaluate is US$ 30/kW (present) or US$ 29/kW (projected). Al/air EVs life-cycle analysis was conducted and compared to lead/acid and nickel metal hydride (NiMH) EVs.