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The main application of diphenyl ether is as a eutectic mixture with biphenyl, used as a heat transfer fluid. Such a mixture is well-suited for heat transfer applications because of the relatively large temperature range of its liquid state. A eutectic mixture (commercially, Dowtherm A) is 73.5% diphenyl ether and 26.5% biphenyl. [9] [10]
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The simplest member of the phenyl ether family is diphenyl ether (DPE), also called diphenyl oxide, the structure of which is provided in Figure 4. Low molecular weight polyphenyl ethers and thioethers are used in a variety of applications, and include high-vacuum devices, optics, electronics, and in high-temperature and radiation-resistant ...
Diethyl ether has higher water solubility of 8 g per 100 mL, versus diphenyl ether, with a solubility of 0.002 g per 100 mL. [3] [4] The presence of the aromatic ring also draws electrons away from the ethereal oxygen, making the hydrolysis of a phenol ether significantly more difficult than that of an alkyl ether. [5]
Celamerck scientists were also working on analogs retaining the 4-nitrodiphenyl ether framework and in 1978 filed a patent of relatively narrow scope which claimed compounds having an amine group adjacent to the nitro substituent and also having an additional chlorine atom between the amine and the oxygen of the diphenyl ether. 2-Chloro-3-phenoxy-6-nitroaniline was described as having ...
Decabromodiphenyl ether (also referred to as decaBDE, DBDE, BDE-209) is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). It was commercialised in the 1970s and was initially thought to be safe, [ 3 ] [ 4 ] but is now recognised as a hazardous and persistent pollutant.
Octabromodiphenyl ether (octaBDE, octa-BDE, OBDE, octa, octabromodiphenyl oxide, OBDPO) is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). Composition, uses, and production
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