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Oxalic acid's main applications include cleaning or bleaching, especially for the removal of rust (iron complexing agent). Its utility in rust removal agents is due to its forming a stable, water-soluble salt with ferric iron, ferrioxalate ion. Oxalic acid is an ingredient in some tooth whitening products.
For example, diethyl oxalate condenses with cyclohexanone to give the diketo-ester, a precursor to pimelic acid. [8] With diamines, the diesters of oxalic acid condense to give cyclic diamides. Quinoxalinedione is produced by condensation of dimethyloxalate and o-phenylenediamine: C 2 O 2 (OMe) 2 + C 6 H 4 (NH 2) 2 → C 6 H 4 (NHCO) 2 + 2 MeOH
It can also be prepared by treating oxalic acid with phosphorus pentachloride. [6] [7] Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination gives the perchloroethylene carbonate C 2 Cl 4 O 2 CO and hydrogen chloride HCl, which is subsequently degraded to oxalyl chloride and phosgene COCl 2: [8] C 2 H 4 O 2 CO + 4 ...
Oxalate oxidase （Enzyme Commission number EC 1.2.3.4 [2] ）occurs mainly in plants. It can degrade oxalic acid into carbon dioxide and hydrogen peroxide. [3]Oxalate decarboxylase (OXDC，EC 4.1.1.2) is a kind of oxalate degrading enzyme containing Mn 2+, [4] found mainly in fungi or some bacteria.
Oxalic acid, also called ethanedioic acid, belongs to the carboxylic acid family. Oxalic acid is used widely as an acid rinse in the laundry industry due to its ability to remove rust and ink stains. Oxalic acid converts insoluble iron compounds into a soluble complex ion. It is because of this property that oxalic acid is one of the primary ...
In enzymology, an oxalate oxidase (EC 1.2.3.4) is an oxalate degrading enzyme that catalyzes the chemical reaction: . oxalate + O 2 + 2 H + 2 CO 2 + H 2 O 2. The 3 substrates of this enzyme are oxalate, O 2, and H +, whereas its two products are CO 2 and H 2 O 2.
Oxalate (systematic IUPAC name: ethanedioate) is an anion with the chemical formula C 2 O 2− 4.This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na 2 C 2 O 4), and several esters such as dimethyl oxalate ((CH 3) 2 C 2 O 4).
It is the sodium salt of oxalic acid. It contains sodium cations Na + and oxalate anions C 2 O 2− 4. It is a white, crystalline, odorless solid, that decomposes above 290 °C. [2] Sodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO 4) solutions.