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Neopentyl glycol (IUPAC name: 2,2-dimethylpropane-1,3-diol) is an organic chemical compound. It is used in the synthesis of polyesters , paints , lubricants , and plasticizers . When used in the manufacture of polyesters, it enhances the stability of the product towards heat, light, and water.
TMP is produced via a two step process, starting with the condensation of butyraldehyde with formaldehyde: CH 3 CH 2 CH 2 CHO + 2 CH 2 O → CH 3 CH 2 C(CH 2 OH) 2 CHO. The second step entails a Cannizaro reaction: CH 3 CH 2 C(CH 2 OH) 2 CHO + CH 2 O + NaOH → CH 3 CH 2 C(CH 2 OH) 3 + NaO 2 CH. Approximately 200,000,000 kg are produced ...
Neopentyl glycol and epichlorohydrin are reacted in the presence of a Lewis acid catalyst to form a halohydrin. This is followed by washing with sodium hydroxide in dehydrochlorination step. This forms Neopentyl glycol diglycidyl ether. [7] The waste products are water and sodium chloride and excess caustic soda.
Pentaerythritol was first reported in 1891 by German chemist Bernhard Tollens and his student P. Wigand. [5] It may be prepared via a base-catalyzed multiple-addition reaction between acetaldehyde and 3 equivalents of formaldehyde to give pentaerythrose (CAS: 3818-32-4), followed by a Cannizzaro reaction with a fourth equivalent of formaldehyde to give the final product plus formate ion.
Trimethylolethane (TME) is the organic compound with the formula CH 3 C(CH 2 OH) 3.This colorless solid is a triol, as it contains three hydroxy functional groups.More specifically, it features three primary alcohol groups in a compact neopentyl structure.
Dibromo neopentyl glycol diglycidyl ether is a brominated version of neopentyl glycol diglycidyl ether. It is an aliphatic organic chemical in the glycidyl ether family that is used in epoxy resin formulations. It has the molecular formula C 11 H 18 Br 2 O 4
The more commonly used polyacids are phthalic, isophthalic, terephthalic and adipic acid. Phthalic and trimellitic anhydrides may also be used. Polyols tend to be neopentyl glycol, 1,6-hexanediol and trimethylolpropane. To make them waterborne organic acids or anhydrides are added in a two-stage process but there are other methods too. [29] [30]
Hydroxypivalic acid neopentyl glycol ester is produced by a Tishchenko reaction from hydroxypivaldehyde in the presence of a basic catalyst (e.g., aluminium oxide). [ 7 ] The Tishchenko reaction of paraformaldehyde in the presence of aluminum methylate or magnesium methylate forms methyl formate .