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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
If a steady-state, steady-flow process is analysed using a control volume, everything outside the control volume is considered to be the surroundings. [2]Such a process will be isenthalpic if there is no transfer of heat to or from the surroundings, no work done on or by the surroundings, and no change in the kinetic energy of the fluid. [3]
For real gasses, the molecules do interact via attraction or repulsion depending on temperature and pressure, and heating or cooling does occur. This is known as the Joule–Thomson effect. For reference, the Joule–Thomson coefficient μ JT for air at room temperature and sea level is 0.22 °C/bar. [7]
This Thomson effect was predicted and later observed in 1851 by Lord Kelvin (William Thomson). [9] It describes the heating or cooling of a current-carrying conductor with a temperature gradient. If a current density J {\displaystyle \mathbf {J} } is passed through a homogeneous conductor, the Thomson effect predicts a heat production rate per ...
The Joule effect (during Joule expansion), the temperature change of a gas (usually cooling) when it is allowed to expand freely. The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. The Gough–Joule effect or ...
This temperature change is known as the Joule–Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy using statistical mechanics as
Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects;
When the potential energy is positive, a constant energy expansion reduces potential energy and increases kinetic energy, resulting in an increase in temperature. This behavior has only been observed for hydrogen and helium; which have very weak attractive interactions. For other gases this "Joule inversion temperature" appears to be extremely ...