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In polymer chemistry, emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomers, and surfactants.The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer (the oil) are emulsified (with surfactants) in a continuous phase of water.
An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation.Emulsions are part of a more general class of two-phase systems of matter called colloids.
In chain-growth (or chain) polymerization, the only chain-extension reaction step is the addition of a monomer to a growing chain with an active center such as a free radical, cation, or anion. Once the growth of a chain is initiated by formation of an active center, chain propagation is usually rapid by addition of a sequence of monomers.
For example, a mixture that is 60% Water and 40% Oil can form an emulsion where the water is the dispersed phase and the oil is the continuous phase if the emulsifier is more soluble in the oil. This is because the continuous phase is the phase that can coalesce the fastest upon mixing, which means it is the phase that can diffuse the ...
Micro-emulsion polymerization: Emulsion polymerization in which the starting system is a micro-emulsion and the final latex comprises colloidal particles of polymer dispersed in an aqueous medium. Note : Diameters of polymer particles formed in the micro-emulsion polymerization usually are between 10 and 50 nm.
A Ramsden emulsion, sometimes named Pickering emulsion, is an emulsion that is stabilized by solid particles (for example colloidal silica) which adsorb onto the interface between the water and oil phases. Typically, the emulsions are either water-in-oil or oil-in-water emulsions, but other more complex systems such as water-in-water, oil-in ...
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My reasoning is that as understanding of emulsion polymerization developed in the 2nd half of the 20th century, fewer and fewer systems were shown to actually follow those kinetics. For example, a lot of diene polymerizations - possibly all of them - display limited particle agglomeration throughout the nominal S-E stage 2, not the unchanging ...