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The concept is the same as for a large mass balance, but it is performed in the context of a limiting system (for example, one can consider the limiting case in time or, more commonly, volume). A differential mass balance is used to generate differential equations that can provide an effective tool for modelling and understanding the target system.
Mass–energy equivalence states that all objects having mass, or massive objects, have a corresponding intrinsic energy, even when they are stationary.In the rest frame of an object, where by definition it is motionless and so has no momentum, the mass and energy are equal or they differ only by a constant factor, the speed of light squared (c 2).
The law also defines the internal energy of a system, an extensive property for taking account of the balance of heat and work in the system. Energy cannot be created or destroyed, but it can be transformed from one form to another. In an isolated system the sum of all forms of energy is constant.
Because it expresses conservation of total energy, this is sometimes referred to as the energy balance equation of continuous media. The first law is used to derive the non-conservation form of the Navier–Stokes equations. [3]
The law of conservation of mass and the analogous law of conservation of energy were finally generalized and unified into the principle of mass–energy equivalence, described by Albert Einstein's equation =. Special relativity also redefines the concept of mass and energy, which can be used interchangeably and are defined relative to the frame ...
Helmholtz free energy: A, F = J ML 2 T −2: Landau potential, Landau free energy, Grand potential: Ω, Φ G = J ML 2 T −2: Massieu potential, Helmholtz free entropy: Φ = / J⋅K −1: ML 2 T −2 Θ −1: Planck potential, Gibbs free entropy: Ξ
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume:
In the general case a conservation equation can be also a system of this kind of equations (a vector equation) in the form: [9]: 43 + = where y is called the conserved (vector) quantity, ∇y is its gradient, 0 is the zero vector, and A(y) is called the Jacobian of the current density.