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The Freundlich isotherm is the most important multi-site adsorption isotherm for rough surfaces. =, where α F and C F are fitting parameters. [14] This equation implies that if one makes a log–log plot of adsorption data, the data will fit a straight line. The Freundlich isotherm has two parameters, while Langmuir's equations has only one ...
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The langmuir (symbol: L) is a unit of exposure (or dosage) to a surface (e.g. of a crystal) and is used in ultra-high vacuum (UHV) surface physics to study the adsorption of gases. It is a practical unit, and is not dimensionally homogeneous , and so is used only in this field.
[1] [2] [nb 1] This equation is formally equivalent to the Langmuir isotherm. [3] Conversely, the Hill equation proper reflects the cellular or tissue response to the ligand: the physiological output of the system, such as muscle contraction.
The CL vortex force is used to explain the generation of Langmuir circulations by an instability mechanism. The CL vortex-force mechanism was derived and studied by Sidney Leibovich and Alex D. D. Craik in the 1970s and 80s, in their studies of Langmuir circulations (discovered by Irving Langmuir in the 1930s).
The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses: gas molecules physically adsorb on a solid in layers infinitely; gas molecules only interact with adjacent layers; and; the Langmuir theory can be applied to each layer.
Reactions on surfaces are reactions in which at least one of the steps of the reaction mechanism is the adsorption of one or more reactants. The mechanisms for these reactions, and the rate equations are of extreme importance for heterogeneous catalysis.
The model applies to gases adsorbed on solid surfaces. It is a semi-empirical isotherm with a kinetic basis and was derived based on statistical thermodynamics. It is the most common isotherm equation to use due to its simplicity and its ability to fit a variety of adsorption data. It is based on four assumptions: