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X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
Extended X-ray absorption fine structure (EXAFS), along with X-ray absorption near edge structure , is a subset of X-ray absorption spectroscopy . Like other absorption spectroscopies , XAS techniques follow Beer's law .
X-ray absorption edge spectroscopy corresponds to the transition from a core-level to an unoccupied orbital or band and mainly reflects the electronic unoccupied states. EXAFS, resulting from the interference in the single scattering process of the photoelectron scattered by surrounding atoms, provides information on the local structure.
X-ray absorption near edge structure (XANES), also known as near edge X-ray absorption fine structure (NEXAFS), is a type of absorption spectroscopy that indicates the features in the X-ray absorption spectra of condensed matter due to the photoabsorption cross section for electronic transitions from an atomic core level to final states in the energy region of 50–100 eV above the selected ...
Surface-extended X-ray absorption fine structure (SEXAFS) is the surface-sensitive equivalent of the EXAFS technique. This technique involves the illumination of the sample by high-intensity X-ray beams from a synchrotron and monitoring their photoabsorption by detecting in the intensity of Auger electrons as a function of the incident photon energy.
Anomalous X-ray scattering (MAD or SAD phasing) – the X-ray wavelength may be scanned past an absorption edge [a] of an atom, which changes the scattering in a known way. By recording full sets of reflections at three different wavelengths (far below, far above and in the middle of the absorption edge) one can solve for the substructure of ...
Pages in category "X-ray absorption spectroscopy" The following 7 pages are in this category, out of 7 total. This list may not reflect recent changes. ...
Indeed, as for X-ray absorption and non-resonant X-ray emission spectroscopy the energy resolution is often limited by the relatively short life-time of the final state core-hole. As in RIXS a high energy core-hole is absent in the final state, this leads to intrinsically sharp spectra with energy and momentum resolution determined by the ...