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The Statue of Liberty, showing advanced patination; verdigris is responsible for the statue's iconic green colour.. Verdigris (/ ˈ v ɜːr d ɪ ɡ r iː (s)/) [1] is a common name for any of a variety of somewhat toxic [2] [3] [4] copper salts of acetic acid, which range in colour from green to a bluish-green depending on their chemical composition.
Similar processes can be found on some ancient Egyptian copper sheets. [3] Another example of early chemical coloring of metals is the Nebra sky disk, which has a green patina and gold inlays. An early example of black colored iron is the famous Celtic spearhead found in the River Thames and dated between 200 and 50 BC.
Figuratively, patina can refer to any fading, darkening, or other signs of age, which are felt to be natural or unavoidable (or both). The chemical process by which a patina forms or is deliberately induced is called patination, and a work of art coated by a patina is said to be patinated. Copper weather vane with verdigris patina
After drying the copper panel was ready for the artist to begin painting. Later artists used the patina process, in which the copper is oxidized with the use of various acidic solutions, as part of the art work itself. The resulting patina or verdigris includes darkening of the metal, green and blue tones, depending on the chemical solution ...
One example of a traditional Japanese patination for mokume-gane is the use of the niiro process, usually involving rokushō, a complex copper verdigris compound produced specifically for use as a patina. The piece to be patinated is prepared, then immersed in a boiling solution until it reaches the desired color, and each element of a compound ...
Basic copper(II) carbonate patina on roofs of Château Frontenac. Basic copper carbonate is prepared by combining aqueous solutions of copper(II) sulfate and sodium carbonate. Basic copper carbonate precipitates from the solution, with release of carbon dioxide CO 2: [7] 2CuSO 4 + 2Na 2 CO 3 + H 2 O → Cu 2 (OH) 2 CO 3 + 2Na 2 SO 4 + CO 2