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The Green Book is a direct successor of the Manual of Symbols and Terminology for Physicochemical Quantities and Units, originally prepared for publication on behalf of IUPAC's Physical Chemistry Division by M. L. McGlashen in 1969. A full history of the Green Book's various editions is provided in the historical introduction to the third edition.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
In the International System of Units (SI), the coherent unit for molar concentration is mol/m 3. However, most chemical literature traditionally uses mol/dm 3, which is the same as mol/L. This traditional unit is often called a molar and denoted by the letter M, for example: 1 mol/m 3 = 10 −3 mol/dm 3 = 10 −3 mol/L = 10 −3 M = 1 mM = 1 ...
A number of different units (some only of historical interest) are shown and expressed in terms of the corresponding SI unit. Conversions between units in the metric system are defined by their prefixes (for example, 1 kilogram = 1000 grams, 1 milligram = 0.001 grams) and are thus not listed in this article.
While not an SI-unit, the litre may be used with SI units. It is equivalent to (10 cm) 3 = (1 dm) 3 = 10 −3 m 3. Many non-SI units continue to be used in the scientific, technical, and commercial literature. Some units are deeply embedded in history and culture, and their use has not been entirely replaced by their SI alternatives.
Like chemists, chemical engineers use the unit mole extensively, but different unit multiples may be more suitable for industrial use. For example, the SI unit for volume is the cubic metre, a much larger unit than the commonly used litre in the chemical laboratory.
For polymers in condensed chemical formulae, parentheses are placed around the repeating unit. For example, a hydrocarbon molecule that is described as CH 3 (CH 2) 50 CH 3, is a molecule with fifty repeating units. If the number of repeating units is unknown or variable, the letter n may be used to indicate this formula: CH 3 (CH 2) n CH 3.