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An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by the German scientist Eugen Goldstein, in 1886. [1] Later work on anode rays by Wilhelm Wien and J. J. Thomson led to the development of mass spectrometry.
Figure 1. Ives–Stilwell experiment (1938). "Canal rays" (a mixture of mostly H 2 + and H 3 + ions) were accelerated through perforated plates charged from 6,788 to 18,350 volts. The beam and its reflected image were simultaneously observed with the aid of a concave mirror offset 7° from the beam. [1] Figure 2.
Eugen Goldstein (/ ˈ ɔɪ ɡ ən / OY-gən, German: [ˈɔʏɡeːn ˈɡɔlt.ʃtaɪn, ˈɔʏɡn̩-]; 5 September 1850 – 25 December 1930) was a German physicist.He was an early investigator of discharge tubes, the discoverer of anode rays or canal rays, later identified as positive ions in the gas phase including the hydrogen ion.
As ionizing radiation moves through matter its energy is deposited through interactions with the electrons of the absorber. [1] The result of an interaction between the radiation and the absorbing species is removal of an electron from an atom or molecular bond to form radicals and excited species. The radical species then proceed to react with ...
Because these latter rays passed through the holes, or channels, in the cathode, Goldstein called them "kanalstrahlen", or canal rays. He determined that canal rays are composed of positive ions whose identity depends on the residual gas inside the tube. It was another of Helmholtz's students, Wilhelm Wien, who later conducted extensive studies ...
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of free electrons among a structure of positively charged ions .
Cathode rays are now usually called electron beams. The technology of manipulating electron beams pioneered in these early tubes was applied practically in the design of vacuum tubes, particularly in the invention of the cathode-ray tube (CRT) by Ferdinand Braun in 1897, which was used in television sets and oscilloscopes .
However, X-ray science has special terminology to describe the transition of electrons from upper to lower energy levels: traditional Siegbahn notation, or alternatively, simplified X-ray notation. In Siegbahn notation, when an electron falls from the L shell to the K shell, the X-ray radiation emitted is called a K-alpha (Kα) emission