Search results
Results From The WOW.Com Content Network
Sodium arsenate is the inorganic compound with the formula Na 3 AsO 4. Related salts are also called sodium arsenate, including Na 2 HAsO 4 (disodium hydrogen arsenate) and NaH 2 AsO 4 (sodium dihydrogen arsenate). The trisodium salt is a white or colourless solid that is highly toxic. It is usually handled as the dodecahydrate Na 3 AsO 4. 12H ...
The other sodium arsenates are NaH 2 AsO 4 and Na 3 AsO 4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid. [1] Being a diprotic acid, its acid-base properties is described by two equilibria: H 2 AsO − 4 + H 2 O ⇌ HAsO 2−
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
Sodium dihydrogen arsenate is a colorless solid that is highly toxic. The salt is the conjugate base of arsenic acid: H 3 AsO 4 ⇌ H 2 AsO − 4 + H + (K 1 = 10 −2.19) In the laboratory, it is prepared in this way, crystallizing from a hot saturated aqueous solution, where it is highly soluble when hot (75.3 g in 100 mL at 100 °C). It is ...
This reaction generates glucose-6-arsenate and 6-arsenogluconate, which act as analogs for glucose-6-phosphate and 6-phosphogluconate. [40] At the substrate level, during glycolysis , glucose-6-arsenate binds as a substrate to glucose-6-phosphate dehydrogenase, and also inhibits hexokinase through negative feedback. [ 40 ]
An arsinide, arsanide, dihydridoarsenate(1−) or arsanyl compound is a chemical derivative of arsine, where one hydrogen atom is replaced with a metal or cation. The arsinide ion has formula AsH − 2. It can be considered as a ligand with name arsenido or arsanido. Few chemists study arsanyl compounds, as they are both toxic and unstable. [1]
Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
The Perkow reaction is a competing reaction pathway for α-bromo- and α-chloroketones. Under the reaction conditions a mixture of the Perkow product and the normal Arbuzov product occur, usually favoring the Perkow product by a significant amount. Using higher temperatures during the reaction can lead to favoring of the Arbuzov product.