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Depending on the environmental conditions present at the time of their formation, concretions can be created by either concentric or pervasive growth. [11] [12] In concentric growth, the concretion grows as successive layers of mineral precipitate around a central core. This process results in roughly spherical concretions that grow with time.
Similar to the marine nodules, concretion layers are defined based on iron and manganese content as well as their combination. [2] High iron content nodules appear a red or brown color, while high manganese content appears black or grey. [2] The dominant metal oxide is related to the elements enriched in the nodule.
The iron forming these concretions came from the breakdown of iron-bearing silicate minerals by weathering to form iron oxide coatings on other grains. During later diagenesis of the Navajo Sandstone while deeply buried, reducing fluids , likely hydrocarbons , dissolved these coatings.
Iron is stored in many organisms in the form of ferritin, which is a ferrous oxide encased in a solubilizing protein sheath. [ 10 ] Species of bacteria , including Shewanella oneidensis , Geobacter sulfurreducens and Geobacter metallireducens , use iron oxides as terminal electron acceptors .
Although channel iron deposits are typically low-grade at 53% to 57% Fe in-situ, they are composed of goethite-limonite which are hydrated iron oxide species. Ore typically contains around 8% to 12% water, and <5% SiO 2, and <3% Al 2 O 3. The hydrous iron oxides can be calcined, and the CID ore on a volatile-free basis is around 63% Fe or more.
Bog iron is a form of impure iron deposit that develops in bogs or swamps by the chemical or biochemical oxidation of iron carried in solution. In general, bog ores consist primarily of iron oxyhydroxides , commonly goethite (FeO(OH)).
Iron oxide copper gold (IOCG) deposits are considered to be metasomatic expressions of large crustal-scale alteration events driven by intrusive activity. The deposit type was first recognised by discovery and study of the supergiant Olympic Dam copper-gold-uranium deposit (Olympic Dam mine), and South American examples.
Iron formations can be divided into subdivisions known as: banded iron formations (BIFs) and granular iron formations (GIFs). [ 3 ] The above classification scheme is the most commonly used and accepted, though sometimes an older system is used which divides iron-rich sedimentary rocks into three categories: bog iron deposits , ironstones , and ...