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The Bohr model is a relatively primitive model of the hydrogen atom, compared to the valence shell model. As a theory, it can be derived as a first-order approximation of the hydrogen atom using the broader and much more accurate quantum mechanics and thus may be considered to be an obsolete scientific theory.
In the end, the model was replaced by the modern quantum-mechanical treatment of the hydrogen atom, which was first given by Wolfgang Pauli in 1925, using Heisenberg's matrix mechanics. The current picture of the hydrogen atom is based on the atomic orbitals of wave mechanics, which Erwin Schrödinger developed in 1926.
Depiction of a hydrogen atom showing the diameter as about twice the Bohr model radius. (Image not to scale) A hydrogen atom is an atom of the chemical element hydrogen.The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb force.
Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot.
In Schrödinger's quantum-mechanical theory of the hydrogen atom, the Bohr radius is the value of the radial coordinate for which the radial probability density of the electron position is highest. The expected value of the radial distance of the electron, by contrast, is 3 2 a 0 {\displaystyle {\tfrac {3}{2}}a_{0}} .
It is worth noting that this expression was first obtained by Sommerfeld based on the old Bohr theory; i.e., before the modern quantum mechanics was formulated. Energy diagram (to scale) of the hydrogen atom for n=2 corrected by the fine structure and magnetic field.
However, for hydrogen alone, in 1927 the Heitler–London theory was formulated which for the first time enabled the calculation of bonding properties of the hydrogen molecule H 2 based on quantum mechanical considerations.