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Tribromide is the anion with the chemical formula Br 3 −, or salts containing it: . Tetrabutylammonium tribromide; Tetrabromophosphonium tribromide; Pyridinium perbromide; Sodium and potassium tribromides can be prepared by reacting NaBr or KBr with aqueous bromine.
Expressing resonance when drawing Lewis structures may be done either by drawing each of the possible resonance forms and placing double-headed arrows between them or by using dashed lines to represent the partial bonds (although the latter is a good representation of the resonance hybrid which is not, formally speaking, a Lewis structure).
In chemistry, the pentazenium cation (also known as pentanitrogen) is a positively-charged polyatomic ion with the chemical formula N + 5 and structure N−N−N−N−N.Together with solid nitrogen polymers and the azide anion, it is one of only three poly-nitrogen species obtained in bulk quantities.
[13] as well as other Lewis bases. The Lewis acid properties of B(CH 3) 3 have been analyzed by the ECW model yielding E A = 2.90 and C A = 3.60. When trimethylborane forms an adduct with trimethylamine, steric repulsion between the methyl groups on the B and N results. The ECW model can provide a measure of this steric effect.
The trihalides adopt a planar trigonal structure. These compounds are Lewis acids in that they readily form adducts with electron-pair donors, which are called Lewis bases. For example, fluoride (F −) and boron trifluoride (BF 3) combined to give the tetrafluoroborate anion, BF 4 −. Boron trifluoride is used in the petrochemical industry as ...
Pyridinium perbromide (also called pyridinium bromide perbromide, pyridine hydrobromide perbromide, or pyridinium tribromide) is an organic chemical composed of a pyridinium cation and a tribromide anion. It can also be considered as a complex containing pyridinium bromide—the salt of pyridine and hydrogen bromide—with an added bromine (Br ...
The Lewis acidity of all the gallium trihalides, GaBr 3 included, has been extensively studied thermodynamically, and the basicity of GaBr 3 has been established with a number of donors. [2] GaBr 3 is capable of accepting an additional Br − ion or unevenly splitting its dimer to form [GaBr 4] −, a tetrahedral ion of which crystalline salts ...
Phosphorus tribromide, like PCl 3 and PF 3, has both properties of a Lewis base and a Lewis acid. For example, with a Lewis acid such as boron tribromide it forms stable 1 :1 adducts such as Br 3 B · PBr 3. At the same time PBr 3 can react as an electrophile or Lewis acid in many of its reactions, for example with amines.