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  2. Sublimation (phase transition) - Wikipedia

    en.wikipedia.org/wiki/Sublimation_(phase_transition)

    Solid carbon dioxide sublimes rapidly along the solid-gas boundary (sublimation point) below the triple point (e.g., at the temperature of −78.5 °C, at atmospheric pressure), whereas its melting into liquid CO 2 can occur along the solid-liquid boundary (melting point) at pressures and temperatures above the triple point (i.e., 5.1 atm, − ...

  3. Sublimatory - Wikipedia

    en.wikipedia.org/wiki/Sublimatory

    The form of the cooled surface often is a so-called cold finger which for very low-temperature sublimation may actually be cryogenically cooled. If the operation is a batch process , then the sublimed material can be collected from the cooled surface once heating ceases and the vacuum is released.

  4. Enthalpy of sublimation - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_of_sublimation

    In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.

  5. Dry ice - Wikipedia

    en.wikipedia.org/wiki/Dry_ice

    The density of dry ice increases with decreasing temperature and ranges between about 1.55 and 1.7 g/cm 3 (97 and 106 lb/cu ft) below 195 K (−78 °C; −109 °F). [3] The low temperature and direct sublimation to a gas makes dry ice an effective coolant, since it is colder than water ice and leaves no residue as it changes state. [4]

  6. Triple point - Wikipedia

    en.wikipedia.org/wiki/Triple_point

    A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]

  7. Cold finger - Wikipedia

    en.wikipedia.org/wiki/Cold_finger

    Cold finger used in sublimation.The raw product (6) is in the bottom of the outer tube (4) which is heated (7) while under vacuum (through side-arm 3). The sublimated material collects (5) on the cold finger proper, cooled by a coolant (blue) circulated through ports 1 and 2.