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  2. Allyl group - Wikipedia

    en.wikipedia.org/wiki/Allyl_group

    A site adjacent to the unsaturated carbon atom is called the allylic position or allylic site. A group attached at this site is sometimes described as allylic. Thus, CH 2 =CHCH 2 OH "has an allylic hydroxyl group". Allylic C−H bonds are about 15% weaker than the C−H bonds in ordinary sp 3 carbon centers and are thus more reactive.

  3. Isocyanide - Wikipedia

    en.wikipedia.org/wiki/Isocyanide

    The C-N distance in isocyanides is 115.8 pm in methyl isocyanide.The C-N-C angles are near 180°. [3]Akin to carbon monoxide, isocyanides are described by two resonance structures, one with a triple bond between the nitrogen and the carbon and one with a double bond between.

  4. Grignard reaction - Wikipedia

    en.wikipedia.org/wiki/Grignard_reaction

    A solution of a carbonyl compound is added to a Grignard reagent. (See gallery) An example of a Grignard reaction (R 2 or R 3 could be hydrogen). The Grignard reaction (French:) is an organometallic chemical reaction in which, according to the classical definition, carbon alkyl, allyl, vinyl, or aryl magnesium halides (Grignard reagent) are added to the carbonyl groups of either an aldehyde or ...

  5. Alkyl group - Wikipedia

    en.wikipedia.org/wiki/Alkyl_group

    Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl. The formula of alkyl radicals are the same as alkyl groups, except the free valence "−" is replaced by the dot "•" and adding "radical" to the name of the alkyl group (e.g. methyl radical •CH 3).

  6. Phenol ether - Wikipedia

    en.wikipedia.org/wiki/Phenol_ether

    Primary alkyl halides work best, as secondary and tertiary alkyl halides prefer the E2 elimination product. [6] This ether synthesis removes the risk of self-condensation, and yields can be as high as 95% in the laboratory. A Williamson ether synthesis between p-ethylphenolate and bromoethane to form 4-ethyl-1-ethoxybenzene.

  7. Barbier reaction - Wikipedia

    en.wikipedia.org/wiki/Barbier_reaction

    The Barbier reaction is an organometallic reaction between an alkyl halide (chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, indium, tin, samarium, barium or their salts. The reaction product is a primary, secondary or tertiary alcohol.