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For white LEDs, a blue LED is used with a yellow phosphor, or with a green and yellow SiAlON phosphor and a red CaAlSiN 3-based (CASN) phosphor. [ 23 ] [ 24 ] [ 25 ] White LEDs can also be made by coating near-ultraviolet-emitting LEDs with a mixture of high-efficiency europium-based red- and blue-emitting phosphors plus green-emitting copper ...
PCl 3 reacts vigorously with water to form phosphorous acid (H 3 PO 3) and hydrochloric acid: PCl 3 + 3 H 2 O → H 3 PO 3 + 3 HCl. Phosphorus trichloride is the precursor to organophosphorus compounds. It reacts with phenol to give triphenyl phosphite: 3 PhOH + PCl 3 → P(OPh) 3 + 3 HCl (Ph = C 6 H 5)
4 Ca 5 (PO 4) 3 F + 18 SiO 2 + 30 C → 3 P 4 + 30 CO + 18 CaSiO 3 + 2 CaF 2 2 Ca 3 (PO 4) 2 + 6 SiO 2 + 10 C → 6 CaSiO 3 + 10 CO + P 4. Side products from the thermal process include ferrophosphorus, a crude form of Fe 2 P, resulting from iron impurities in the mineral precursors. The silicate slag is a useful construction material.
Phosphorus tribromide, like PCl 3 and PF 3, has both properties of a Lewis base and a Lewis acid. For example, with a Lewis acid such as boron tribromide it forms stable 1 :1 adducts such as Br 3 B · PBr 3. At the same time PBr 3 can react as an electrophile or Lewis acid in many of its reactions, for example with amines.
Phosphorous acid (or phosphonic acid) is the compound described by the formula H 3 PO 3. This acid is diprotic (readily ionizes two protons), not triprotic as might be suggested by this formula. Phosphorous acid is an intermediate in the preparation of other phosphorus compounds.
With a gyromagnetic ratio 40.5% of that for 1 H, 31 P-NMR signals are observed near 202 MHz on an 11.7-Tesla magnet (used for 500 MHz 1 H-NMR measurements). Chemical shifts are typically referenced to 85% phosphoric acid, which is assigned the chemical shift of 0, and appear at positive values (downfield of the standard). [2]
Phosphor bronze propeller salvaged from 1940s American warship.. Phosphor bronze is a member of the family of copper alloys.It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties (e.g. lead at 0.5–3.0% to form free-machining phosphor bronze).
The phosphate is present as fluorapatite Ca 5 (PO 4) 3 F typically in cryptocrystalline masses (grain sizes < 1 μm) referred to as collophane-sedimentary apatite deposits of uncertain origin. [2] It is also present as hydroxyapatite Ca 5 (PO 4 ) 3 OH or Ca 10 (PO 4 ) 6 (OH) 2 , which is often dissolved from vertebrate bones and teeth, whereas ...