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The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule.It is a better approximation for the vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states.
The lattice mode potential energy in Figure 6 is represented as that of a harmonic oscillator, and the spacing between phonon levels is determined by lattice parameters. Because the energy of single phonons is generally quite small, zero- or few-phonon transitions can only be observed at temperatures below about 40 kelvins .
The Morse potential (blue) and harmonic oscillator potential (green). The potential at infinite internuclear distance is the dissociation energy for pure vibrational spectra. For vibronic spectra there are two potential curves (see Figure at right), and the dissociation limit is the upper state energy at infinite distance.
The potential-energy function of a harmonic oscillator is =. Given an arbitrary potential-energy function V ( x ) {\displaystyle V(x)} , one can do a Taylor expansion in terms of x {\displaystyle x} around an energy minimum ( x = x 0 {\displaystyle x=x_{0}} ) to model the behavior of small perturbations from equilibrium.
This is a list of potential energy functions that are frequently used in quantum mechanics ... Harmonic potential (harmonic oscillator) Morse potential (morse oscillator)
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The rectangular potential barrier; The triangular potential; The quadratic potentials The quantum harmonic oscillator; The quantum harmonic oscillator with an applied uniform field [1] The Inverse square root potential [2] The periodic potential The particle in a lattice; The particle in a lattice of finite length [3] The Pöschl–Teller potential
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point , it is one of the most important model systems in quantum mechanics.