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Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
tert-Butyl alcohol is the simplest tertiary alcohol, with a formula of (CH 3) 3 COH (sometimes represented as t-BuOH). Its isomers are 1-butanol, isobutanol, and butan-2-ol. tert-Butyl alcohol is a colorless solid, which melts near room temperature and has a camphor-like odor. It is miscible with water, ethanol and diethyl ether.
Three of these alcohols, 2-methyl-1-butanol, 2-pentanol, and 3-methyl-2-butanol (methyl isopropyl carbinol), contain stereocenters, and are therefore chiral and optically active. The most important amyl alcohol is isoamyl alcohol , the chief one generated by fermentation in the production of alcoholic beverages and a constituent of fusel oil .
Butan-2-yl (sec-butyl) group is chiral. The carbon atom at position 2 is a stereocenter. It has four different groups attached: −H, −CH 3, −CH 2 −CH 3, and −R (the R group is not equal to those three groups). The names of the two chiral groups are: (2S)-butan-2-yl and (2R)-butan-2-yl.
Phenethyl alcohol, or 2-phenylethanol, is an organic compound with the chemical formula C 6 H 5 CH 2 CH 2 OH. It is a colourless liquid with a pleasant floral odor. It occurs widely in nature, being found in a variety of essential oils. It is slightly soluble in water (2 ml per 100 ml of H 2 O), but miscible with most organic solvents.
2,3-Butanediol is the organic compound with the formula (CH 3 CHOH) 2. It is classified as a vic -diol ( glycol ). It exists as three stereoisomers, a chiral pair and the meso isomer.
Like other butanols, butan-2-ol has low acute toxicity. The LD 50 is 4400 mg/kg (rat, oral). [6]Several explosions have been reported [7] [8] [9] during the conventional distillation of 2-butanol, apparently due to the buildup of peroxides with the boiling point higher than that of pure alcohol (and therefore concentrating in the still pot during distillation).
Isobutanol (IUPAC nomenclature: 2-methylpropan-1-ol) is an organic compound with the formula (CH 3) 2 CHCH 2 OH (sometimes represented as i-BuOH).This colorless, flammable liquid with a characteristic smell is mainly used as a solvent either directly or as its esters.