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London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds [1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically symmetric; that is, the electrons are ...
Dispersion forces keep the molecule inert even while its core Si-Si bond lengthens. Similarly, the longest known Ge-Ge bond is found in t Bu 3 GeGe t Bu 3 and is also facilitated by dispersion stabilization. [19] Dispersion stabilization has also been invoked for (t BuC) 3 P, a main group analog of a hydrocarbon tetrahedrane. [20]
London dispersion forces are also known as 'dispersion forces', 'London forces', or 'instantaneous dipole–induced dipole forces'. The strength of London dispersion forces is proportional to the polarizability of the molecule, which in turn depends on the total number of electrons and the area over which they are spread.
The dispersion (London) force is the most important component because all materials are polarizable, whereas Keesom and Debye forces require permanent dipoles. The London interaction is universal and is present in atom-atom interactions as well. For various reasons, London interactions (dispersion) have been considered relevant for interactions ...
Hexane is a good example of a molecule with no polarity or highly electronegative atoms, yet is a liquid at room temperature due mainly to London dispersion forces. In this example, when one hexane molecule approaches another, a temporary, weak partially negative dipole on the incoming hexane can polarize the electron cloud of another, causing ...
The cohesive forces that bind the molecules together are van der Waals forces, dipole–dipole interactions, quadrupole interactions, π–π interactions, hydrogen bonding, halogen bonding, London dispersion forces, and in some molecular solids, coulombic interactions.
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The source of adhesive forces, according to the dispersive adhesion mechanism, is the weak interactions that occur between molecules close together. [2] These interactions include London dispersion forces, Keesom forces, Debye forces and hydrogen bonds. Individually, these attractions are not very strong, but when summed over the bulk of a ...