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Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
Arsenic is used as the group 5 element in the III-V semiconductors gallium arsenide, indium arsenide, and aluminium arsenide. [41] The valence electron count of GaAs is the same as a pair of Si atoms, but the band structure is completely different which results in distinct bulk properties. [42]
The group 1 alkali metals and the group 2, alkaline earth metals, form arsenides with isolated arsenic atoms. They form upon heating arsenic powder with excess sodium gives sodium arsenide (Na 3 As). The structure of Na 3 As is complex with unusually short Na–Na distances of 328–330 pm which are shorter than in sodium metal.
The arsenate is an ion with the chemical formula AsO 3− 4. [1] Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. [2] The four oxygen atoms orient around the arsenic atom in a tetrahedral geometry. [2]
The old (but extremely sensitive) Marsh test generates AsH 3 in the presence of arsenic. [4] This procedure, published in 1836 by James Marsh, [18] is based upon treating an As-containing sample of a victim's body (typically the stomach contents) with As-free zinc and dilute sulfuric acid: if the sample contains arsenic, gaseous arsine will ...
These are mixed anion compounds or mixed valence compounds. Some have third anions. Most known substances are minerals, but a few artificial arsenate arsenite compounds have been made. Many of the minerals are in the Hematolite Group. An arsenate arsenite compound may also be called an arsenite arsenate.
It can also be prepared by chlorination of arsenic at 80–85 °C, but this method requires elemental arsenic. [4] 2 As + 3 Cl 2 → 2 AsCl 3. Arsenic trichloride can be prepared by the reaction of arsenic oxide and sulfur monochloride. This method requires simple apparatus and proceeds efficiently: [8] 2 As 2 O 3 + 6 S 2 Cl 2 → 4 AsCl 3 + 3 ...
Trimethylarsine (abbreviated TMA or TMAs) is the chemical compound with the formula (CH 3) 3 As, commonly abbreviated AsMe 3 or TMAs. This organic derivative of arsine has been used as a source of arsenic in microelectronics industry, [1] a building block to other organoarsenic compounds, and serves as a ligand in coordination chemistry.