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An adiabatic process (adiabatic from Ancient Greek ἀδιάβατος (adiábatos) 'impassable') is a type of thermodynamic process that occurs without transferring heat between the thermodynamic system and its environment. Unlike an isothermal process, an adiabatic process transfers energy to the surroundings only as work and/or mass flow.
For example, terrestrial air is primarily made up of diatomic gases (around 78% nitrogen, N 2, and 21% oxygen, O 2), and at standard conditions it can be considered to be an ideal gas. The above value of 1.4 is highly consistent with the measured adiabatic indices for dry air within a temperature range of 0–200 °C, exhibiting a deviation of ...
Effects of dissociation on adiabatic flame temperature. In real world applications, complete combustion does not typically occur. Chemistry dictates that dissociation and kinetics will change the composition of the products. There are a number of programs available that can calculate the adiabatic flame temperature taking into account ...
Adiabatic process: occurs without loss or gain of energy by heat; Isenthalpic process: occurs at a constant enthalpy; Isentropic process: a reversible adiabatic process, occurs at a constant entropy; Isobaric process: occurs at constant pressure; Isochoric process: occurs at constant volume (also called isometric/isovolumetric)
If the calorically perfect gas approximation is used, then the ideal gas law may also be expressed as follows = where is the number density of the gas (number of atoms/molecules per unit volume), = / is the (constant) adiabatic index (ratio of specific heats), = is the internal energy per unit mass (the "specific internal energy"), is the ...
Ratio of isobaric to isochoric heat capacity, heat capacity ratio, adiabatic index, Laplace coefficient ... (for diatomic ideal gas) Internal Energy
Commercial calorimeters operate in a similar way. The semi-adiabatic (isoperibol) calorimeters measure temperature changes up to 10 −6 °C and account for heat loss through the walls of the reaction vessel to the environment, hence, semi-adiabatic. The reaction vessel is a dewar flask which is immersed in a constant temperature bath.
One mole of atoms contains an Avogadro number of atoms, so that the energy of one mole of atoms of a monatomic gas is =, where R is the gas constant. In an adiabatic process, monatomic gases have an idealised γ-factor (C p /C v) of 5/3, as opposed to 7/5 for ideal diatomic gases where rotation (but not vibration at room temperature) also ...