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The only hydrates with stable melting points are NaOH·H 2 O (65.10 °C) and NaOH·3.5H 2 O (15.38 °C). The other hydrates, except the metastable ones NaOH·3H 2 O and NaOH·4H 2 O (β) can be crystallized from solutions of the proper composition, as listed above. However, solutions of NaOH can be easily supercooled by many degrees, which ...
White liquor consists mainly of sodium hydroxide and sodium sulfide in water and is the active component in Kraft pulping. [1] White liquor also contains minor amounts of sodium carbonate, sodium sulfate, sodium thiosulfate, sodium chloride, calcium carbonate and other accumulated salts and non-process elements.
Similarly, potassium hydroxide is available as a solution used for cleaning terraces and other areas made out of wood. Both NaOH and KOH are also used in the production of soap and detergents (saponification). Due to their hygroscopic properties, alkali hydroxides are used as desiccants.
TMAH is a stable compound, with a half-life longer than 61 h in 6 M NaOH at 160 °C. [5] TMAH undergoes simple acid-base reactions to produce tetramethylammonium (TMA) salts whose anion is derived from the acid used. Illustrative is the preparation of tetramethylammonium fluoride: [6] NMe 4 + OH − + HF → NMe 4 + F − + H 2 O
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H 3 PO 4 + 2 NaOH → Na 2 HPO 4 + 2 H 2 O. Industrially It is prepared in a two-step process by treating dicalcium phosphate with sodium bisulfate, which precipitates calcium sulfate: [2] CaHPO 4 + NaHSO 4 → NaH 2 PO 4 + CaSO 4. In the second step, the resulting solution of monosodium phosphate is partially neutralized: NaH 2 PO 4 + NaOH → ...