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In its uncured state, silicone rubber is a highly adhesive gel or liquid. To convert it to a solid, it must be cured, vulcanized, or catalyzed.This is normally carried out in a two-stage process at the point of manufacture into the desired shape, and then in a prolonged post-cure process.
Silicone caulk can be used as a basic sealant against water and air penetration. In organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (−O−R 2 Si−O−SiR 2 −, where R = organic group).
Caulk (also known as caulking and calking) [1] is a material used to seal joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibrous materials driven into the wedge-shaped seams between boards on wooden boats or ships. Cast iron sewerage pipes were formerly caulked in a similar way.
A caulking sealant has three basic functions: It fills a gap between two or more substrates; it forms a barrier due to the physical properties of the sealant itself and by adhesion to the substrate; and it maintains sealing properties for the expected lifetime, service conditions, and environments.
RTV silicone rubber can be used to cast materials including wax, gypsum, low-melt alloys/metals, and urethane, epoxy, or polyester resins (without using a release agent). A more recent innovation is the ability to 3D print RTV silicones.
DAP was the first to the market with the introduction of latex caulk in 1964, and since then the company has introduced numerous other caulks, sealants, insulating foams and other patch and repair products. They followed with acrylic latex technology in 1970 and silicone sealants in the mid-1980s.