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Organotin chemistry is the scientific study of the synthesis and properties of organotin compounds or stannanes, which are organometallic compounds containing tin–carbon bonds. The first organotin compound was diethyltin diiodide ( (CH 3 CH 2 ) 2 SnI 2 ), discovered by Edward Frankland in 1849. [ 1 ]
It also reduces copper(II) to copper(I). Solutions of tin(II) chloride can also serve simply as a source of Sn 2+ ions, which can form other tin(II) compounds via precipitation reactions. For example, reaction with sodium sulfide produces the brown/black tin(II) sulfide: SnCl 2 (aq) + Na 2 S (aq) → SnS (s) + 2 NaCl (aq)
Tin(II) hydroxide – Sn(OH) 2; Tin(II) iodide – SnI 2; Tin(II) oxide – SnO; Tin(II) sulfate – SnSO 4; Tin(II) sulfide – SnS; Tin(IV) bromide – SnBr 4; Tin(IV) chloride – SnCl 4; Tin(IV) fluoride – SnF 4; Tin(IV) iodide – SnI 4; Tin(IV) oxide – SnO 2; Tin(IV) sulfide – SnS 2; Tin(IV) cyanide – Sn(CN) 4; Tin selenide ...
Compounds that contain a carbon-copper bond are known as organocopper compounds. They are very reactive towards oxygen to form copper(I) oxide and have many uses in chemistry . They are synthesized by treating copper(I) compounds with Grignard reagents , terminal alkynes or organolithium reagents ; [ 12 ] in particular, the last reaction ...
Tin(II) sulfate (Sn S O 4) is a chemical compound. It is a white solid that can absorb enough moisture from the air to become fully dissolved, forming an aqueous solution; this property is known as deliquescence. It can be prepared by a displacement reaction between metallic tin and copper(II) sulfate: [3] Sn (s) + CuSO 4 (aq) → Cu (s) + SnSO ...
Some metal hydrides form when a metal complex is treated with hydrogen in the presence of a base. The reaction involves no changes in the oxidation state of the metal and can be viewed as splitting H 2 into hydride (which binds to the metal) and proton (which binds to the base). ML n x+ + base + H 2 ⇌ HML n (x-1)+ + Hbase +
When not cooled below −5 °C (23 °F), copper hydride decomposes, to produce hydrogen gas and a mixture containing elemental copper: 2 CuH → xCu•(2-x)CuH + ½x H 2 (0 < x < 2) Solid copper hydride is the irreversible autopolymerisation product of the molecular form, and the molecular form cannot be isolated in concentration.
Tin(II) oxide burning. Blue-black SnO can be produced by heating the tin(II) oxide hydrate, SnO·xH 2 O (x<1) precipitated when a tin(II) salt is reacted with an alkali hydroxide such as NaOH. [4] Metastable, red SnO can be prepared by gentle heating of the precipitate produced by the action of aqueous ammonia on a tin(II) salt. [4]