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Based on molecular orbital theory, He 2 should not exist, and a chemical bond cannot form between the atoms. However, the van der Waals force exists between helium atoms as shown by the existence of liquid helium, and at a certain range of distances between atoms the attraction exceeds the repulsion.
In Earth's atmosphere, the ratio of 3 He to 4 He is 1.343(13) × 10 −6. [5] However, the isotopic abundance of helium varies greatly depending on its origin. In the Local Interstellar Cloud , the proportion of 3 He to 4 He is 1.62(29) × 10 −4 , [ 6 ] which is ~121 times higher than in Earth's atmosphere.
[132] [133] The concentration is low and fairly constant despite the continuous production of new helium because most helium in the Earth's atmosphere escapes into space by several processes. [134] [135] [136] In the Earth's heterosphere, a part of the upper atmosphere, helium and hydrogen are the most abundant elements.
At pressure of 1 atmosphere, the transition occurs at approximately 2.17 K. The lowest pressure at which He-I and He-II can coexist is the vapor−He-I−He-II triple point at 2.1768 K (−270.9732 °C) and 5.0418 kPa (0.049759 atm), which is the "saturated vapor pressure " at that temperature (pure helium gas in thermal equilibrium over the ...
Larger protonated helium cluster ions exist He n H + with n from 3 to 14. He 6 H + and He 13 H + appear to be more common. These can be made by reacting H + 2 or H + 3 with gaseous helium. [70] HeH 2+ is unstable in its ground state. But when it is excited to the 2pσ state the molecule is bound with an energy of 20 kcal/mol.
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures.Liquid helium may show superfluidity.. At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of −269 °C (−452.20 °F; 4.15 K).
The left column shows MO's which are occupied in the ground state, with the lowest-energy orbital at the top. The white and grey line visible in some MO's is the molecular axis passing through the nuclei. The orbital wave functions are positive in the red regions and negative in the blue.
The helium-3, in liquid state at 3.2 K, can be evaporated into the superfluid helium-4, where it acts as a gas due to the latter's properties as a Bose–Einstein condensate. This evaporation pulls energy from the overall system, which can be pumped out in a way completely analogous to normal refrigeration techniques.