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v. t. e. In chemistry and physics, Raman scattering or the Raman effect (/ ˈrɑːmən /) is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser ...
Therefore, the Raman spectrum (scattering intensity as a function of the frequency shifts) depends on the rovibronic states of the molecule. The Raman effect is based on the interaction between the electron cloud of a sample and the external electric field of the monochromatic light, which can create an induced dipole moment within the molecule ...
Fermi resonance leads to two effects. First, the high-energy mode shifts to higher energy, and the low-energy mode shifts to still lower energy. Second, the weaker mode gains intensity (becomes more allowed), and the more intense band decreases in intensity. The two transitions are describable as a linear combination of the parent modes.
Stimulated Raman spectroscopy, also referred to as stimulated Raman scattering (SRS), is a form of spectroscopy employed in physics, chemistry, biology, and other fields. . The basic mechanism resembles that of spontaneous Raman spectroscopy: a pump photon, of the angular frequency , which is scattered by a molecule has some small probability of inducing some vibrational (or rotational ...
Raman amplification / ˈrɑːmən / [1] is based on the stimulated Raman scattering (SRS) phenomenon, when a lower frequency 'signal' photon induces the inelastic scattering of a higher-frequency 'pump' photon in an optical medium in the nonlinear regime. As a result of this, another 'signal' photon is produced, with the surplus energy ...
File:Pure Rotational Raman Spectrum (2).pdf. Size of this JPG preview of this PDF file: 463 × 599 pixels. Other resolutions: 185 × 240 pixels | 371 × 480 pixels | 593 × 768 pixels | 1,275 × 1,650 pixels. This is a file from the Wikimedia Commons. Information from its description page there is shown below.
Resonance Raman spectroscopy (RR spectroscopy or RRS) is a variant of Raman spectroscopy in which the incident photon energy is close in energy to an electronic transition of a compound or material under examination. [1] This similarity in energy (resonance) leads to greatly increased intensity of the Raman scattering of certain vibrational ...
Raman microscopy, and in particular confocal microscopy, can reach down to sub-micrometer lateral spatial resolution. [7] Because a Raman microscope is a diffraction-limited system, its spatial resolution depends on the wavelength of light and the numerical aperture of the focusing element. In confocal Raman microscopy, the diameter of the ...