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A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke .
Thermal cracking is currently used to "upgrade" very heavy fractions or to produce light fractions or distillates, burner fuel and/or petroleum coke. Two extremes of the thermal cracking in terms of the product range are represented by the high-temperature process called "steam cracking" or pyrolysis (ca. 750 °C to 900 °C or higher) which ...
Needle coke, also called acicular coke, is a highly crystalline petroleum coke used in the production of electrodes for the steel and aluminium industries and is particularly valuable because the electrodes must be replaced regularly. Needle coke is produced exclusively from either fluid catalytic cracking (FCC) decant oil or coal tar pitch.
Thermal depolymerization differs in that it contains a hydrous process followed by an anhydrous cracking / distillation process. Condensation polymers bearing cleavable groups such as esters and amides can also be completely depolymerized by hydrolysis or solvolysis; this can be a purely chemical process but may also be promoted by enzymes. [31]
A schematic diagram of a Visbreaker unit. The term coil (or furnace) visbreaking is applied to units where the cracking process occurs in the furnace tubes (or "coils")."). Material exiting the furnace is quenched to halt the cracking reactions: frequently this is achieved by heat exchange with the virgin material being fed to the furnace, which in turn is a good energy efficiency step, but ...
Shukhov designed and built the first thermal cracking device for the petrochemical industry.His patent (Shukhov cracking process – patent of Russian Empire No. 12926 from November 27, 1891) on cracking was used to invalidate Standard Oil's patents (Burton process – Patent of United States No. 1,049,667 on January 7, 1913) on oil refineries.
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In the design shown in Figure 1, the coke has only been partially combusted to CO 2. The combustion flue gas (containing CO and CO 2) at 715 °C and at a pressure of 2.41 bar is routed through a secondary catalyst separator containing swirl tubes designed to remove 70 to 90 percent of the particulates in the flue gas leaving the regenerator. [10]