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When silicon (Si), having four valence electrons, is doped with elements from group III of the periodic table, such as boron (B) and aluminium (Al), both having three valence electrons, a p-type semiconductor is formed. These dopant elements represent trivalent impurities. Other trivalent dopants include indium (In) and gallium (Ga). [1]
A compound semiconductor is a semiconductor compound composed of chemical elements of at least two different species. These semiconductors form for example in periodic table groups 13–15 (old groups III–V), for example of elements from the Boron group (old group III, boron, aluminium, gallium, indium) and from group 15 (old group V, nitrogen, phosphorus, arsenic, antimony, bismuth).
Doping of a pure silicon array. Silicon based intrinsic semiconductor becomes extrinsic when impurities such as boron and antimony are introduced.. In semiconductor production, doping is the intentional introduction of impurities into an intrinsic (undoped) semiconductor for the purpose of modulating its electrical, optical and structural properties.
Impurity atoms are classified as either donor or acceptor atoms based on the effect they have on the intrinsic semiconductor. Donor impurity atoms have more valence electrons than the atoms they replace in the intrinsic semiconductor lattice. Donor impurities "donate" their extra valence electrons to a semiconductor's conduction band, providing ...
The conductivity of semiconductors may easily be modified by introducing impurities into their crystal lattice. The process of adding controlled impurities to a semiconductor is known as doping . The amount of impurity, or dopant, added to an intrinsic (pure) semiconductor varies its level of conductivity. [ 26 ]
In semiconductor physics, a donor is a dopant atom that, when added to a semiconductor, can form a n-type region. Phosphorus atom acting as a donor in the simplified 2D silicon lattice. For example, when silicon (Si), having four valence electrons , is to be doped as a n-type semiconductor , elements from group V like phosphorus (P) or arsenic ...
In semiconductor physics, the depletion region, also called depletion layer, depletion zone, junction region, space charge region, or space charge layer, is an insulating region within a conductive, doped semiconductor material where the mobile charge carriers have diffused away, or been forced away by an electric field. The only elements left ...
This allows us to treat the original semiconductor as unaffected in its electronic properties, with the impurity atoms only increasing the electron concentration. A limit to donor concentration in order to allow treatment as shallow donors is approximately 10 19 cm −3. Energy levels due to impurities deeper in the bandgap are called deep levels.