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miscible polymer blends (homogeneous polymer blends): Polymer blend that is a single-phase structure. In this case, one glass transition temperature will be observed. The use of the term polymer alloy for a polymer blend is discouraged, as the former term includes multiphase copolymers but excludes incompatible polymer blends. [3]
Novel polymeric alloy (NPA) is a polymeric alloy composed of polyolefin and thermoplastic engineering polymer with enhanced engineering properties. NPA was developed for use in geosynthetics . One of the first commercial NPA applications was in the manufacturer of polymeric strips used to form Neoloy® cellular confinement systems (geocells) .
As in metal alloys the properties of a TPO product depend greatly upon controlling the size and distribution of the microstructure. PP and PE form lamellar crystallites separated by amorphous regions that can grow into a variety of microstructures ranging from single crystals from dilute solution crystallization to fiberous crystals and shish ...
In polymer chemistry, compatibilization is the addition of a substance to an immiscible blend of polymers that will increase their stability. Polymer blends are typically described by coarse, unstable phase morphologies; this results in poor mechanical properties. Compatibilizing the system will make a more stable and better blended phase ...
, where ΔS is the change in entropy of mixing, R is the gas constant, Φ is the volume fraction of each polymer, and x is the number of segments of each polymer. [3] x 1 and x 2 increase with higher degrees of polymerization and thus molecular weight. Since most useful polymers are high in molecular weight, the change in entropy experienced ...
A step-growth copolymer -(-A-A-B-B-) n - formed by the condensation of two bifunctional monomers A–A and B–B is in principle a perfectly alternating copolymer of these two monomers, but is usually considered as a homopolymer of the dimeric repeat unit A-A-B-B. [6] An example is nylon 66 with repeat unit -OC-( CH 2) 4-CO-NH-(CH 2) 6-NH ...
A polymer is a substance composed of macromolecules. The latter usually have a range of molar masses (unit g mol −1 ), the distributions of which are indicated by dispersity ( Đ ). It is defined as the ratio of the mass-average molar mass ( M m ) to the number-average molar mass ( M n ) i.e. Đ = M m / M n . [ 4 ]
formed polymer beyond a critical molecular weight. [ 1 ] In polymer science , precipitation polymerization is a heterogeneous polymerization process that begins initially as a homogeneous system in the continuous phase, where the monomer and initiator are completely soluble, but upon initiation the formed polymer is insoluble and thus precipitates.