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In 2024, NTA reduced JEE Main syllabus to reduce pressure and stress among students and to meet the same syllabus structure as that of the NCERT revised books. In the latest 2025 Information brochure, the syllabus remained same as of 2024 but NTA reduced the number of question in Section - B of Paper - 1 (B.E/B-Tech) from 5 out 10 questions (to ...
JEE-Main, unlike JEE-Advanced, has a fixed exam structure and is not subject to change every year. Up until 2018, the JEE-Main Paper-I was three hours long and consisted of thirty questions in each of the three subjects (physics, chemistry and maths). 4 marks are awarded for correct answers and 1 mark is deducted for incorrect answers.
The Darzens reaction (also known as the Darzens condensation or glycidic ester condensation) is the chemical reaction of a ketone or aldehyde with an α-haloester in the presence of a base to form an α,β-epoxy ester, also called a "glycidic ester".
However, with 2022 JEE-Main being postponed from April/May to 20–29 June/21–30 July, JEE-Advanced 2022 was also postponed and subsequently held on 28 August 2022. On 5 November 2024, it was announced by IIT Kanpur , and Joint Admission Board(JAB) that the attempts of JEE-Advanced are now increased from 2 to 3. [ 72 ]
The general structure is RR′C(X)C(=O)R where R is an alkyl or aryl residue and X any one of the halogens. The preferred conformation of a halo ketone is that of a cisoid with the halogen and carbonyl sharing the same plane as the steric hindrance with the carbonyl alkyl group is generally larger.
The reaction is named after Cläre Hunsdiecker and her husband Heinz Hunsdiecker, whose work in the 1930s [5] [6] developed it into a general method. [1]The reaction was first demonstrated by Alexander Borodin in 1861 in his reports of the preparation of methyl bromide (CH 3 Br) from silver acetate (CH 3 CO 2 Ag).
Halothane, sold under the brand name Fluothane among others, is a general anaesthetic. [5] It can be used to induce or maintain anaesthesia. [5] One of its benefits is that it does not increase the production of saliva, which can be particularly useful in those who are difficult to intubate. [5]
In general, the reaction of a haloalkane with potassium hydroxide can compete with an S N 2 nucleophilic substitution reaction by OH − a strong, unhindered nucleophile. Alcohols are however generally minor products. Dehydrohalogenations often employ strong bases such as potassium tert-butoxide (K + [CH 3] 3 CO −).