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Black oxide or blackening is a conversion coating for ferrous materials, stainless steel, copper and copper based alloys, zinc, powdered metals, and silver solder. [1] It is used to add mild corrosion resistance, for appearance, and to minimize light reflection. [ 2 ]
The "hot" process is an alkali salt solution using potassium nitrite or sodium nitrate and sodium hydroxide, referred to as "traditional caustic black", that is typically done at an elevated temperature, 135 to 155 °C (275 to 311 °F). This method was adopted by larger firearm companies for large scale, more economical bluing.
The metal to color should be completely free from oxide and grease. Protective clothing, gloves and goggles should be used in a well-ventilated area or outdoors. Black for silver . Items are immersed in a 2.5% solution of potassium or sodium sulfide, after the appearance of the color wash objects well and wax or varnish it. [26]
Rust converters are chemical solutions or primers that can be applied directly to an iron or iron alloy surface to convert iron oxides into a protective chemical barrier. These compounds interact with iron oxides, especially iron(III) oxide , converting them into an adherent black layer ( black oxide ) that is more resistant to moisture and ...
Blackening (chemistry) or black oxide, a conversion coating for ferrous materials; Blackening (cooking), a cooking technique commonly used in the preparation of fish; Blackening (Scottish wedding custom), performed in the days or weeks prior to marriages in Scotland
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A phosphate coating is usually obtained by applying to the steel part a dilute solution of phosphoric acid, possibly with soluble iron, zinc, and/or manganese salts. The solution may be applied by sponging, spraying, or immersion. [6] Phosphate conversion coatings can also be used on aluminium, zinc, cadmium, silver and tin. [7] [8]
For alloys containing transition metal elements there is a difficulty in interpretation of the Hume-Rothery electron concentration rule, as the values of e/a values (number of itinerant electrons per atom) for transition metals have been quite controversial for a long time, and no satisfactory solutions have yet emerged. [9] [10]