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The work function depends on the configurations of atoms at the surface of the material. For example, on polycrystalline silver the work function is 4.26 eV, but on silver crystals it varies for different crystal faces as (100) face: 4.64 eV, (110) face: 4.52 eV, (111) face: 4.74 eV. [13] Ranges for typical surfaces are shown in the table below ...
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
In solution chemistry and biochemistry, the Gibbs free energy decrease (∂G/∂ξ, in molar units, denoted cryptically by ΔG) is commonly used as a surrogate for (−T times) the global entropy produced by spontaneous chemical reactions in situations where no work is being done; or at least no "useful" work; i.e., other than perhaps ± P dV.
Thus, half the work lifts the piston mass (work of gravity, or “useable” work), while the other half expands the surroundings. The results of these two process examples illustrate the difference between the fraction of heat converted to usable work (mgΔh) vs. the fraction converted to pressure-volume work done against the surrounding ...
Should the work be added in such a way that friction or viscous forces are operating within the system, then the process is not isentropic, and if there is no phase change, then the temperature of the system will rise, the process is said to be "irreversible", and the work added to the system is not entirely recoverable in the form of work.
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes.The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter.
In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:
Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the ...