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For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1. For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance. This is true for ideal solutions only, as occasionally ion pairing occurs in solution. At a given instant a small ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
The third of seven children, van 't Hoff was born in Rotterdam, Netherlands, 30 August 1852. His father was Jacobus Henricus van 't Hoff Sr., a physician, and his mother was Alida Kolff van 't Hoff. [10] From a young age, he was interested in science and nature, and frequently took part in botanical excursions.
In 1884, Jacobus van 't Hoff proposed the Van 't Hoff equation describing the temperature dependence of the equilibrium constant for a reversible reaction: = where ΔU is the change in internal energy, K is the equilibrium constant of the reaction, R is the universal gas constant, and T is thermodynamic temperature.
He later added a third dimension, psychoticism, resulting in his "P-E-N" three factor model of personality. This has been correlated with two separate factors developed by the Big Five personality traits (Five Factor Model), called "agreeableness" and "conscientiousness"; the former being similar to the people/task orientation scale elaborated ...
The Pathoplasty Model: This model proposes that premorbid personality traits impact the expression, course, severity, and/or treatment response of a mental disorder. [194] [200] [81] An example of this relationship would be a heightened likelihood of committing suicide in a depressed individual who also has low levels of constraint. [200]
The Personality Assessment System (PAS) is a descriptive model of personality formulated by John W. Gittinger. The system has been used by scientists in studying personality and by clinicians in clinical practice. A major feature of the PAS is that a personality profile can be systematically interpreted from a set of Wechsler Scales subtest ...