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Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [ 1 ] [ 2 ] It is an important type of alkaline hydrolysis .
[1] [2] [3] It is a measure of the average molecular weight (or chain length) of all the fatty acids present in the sample in form of triglycerides. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa.
Perhaps the oldest commercially practiced example of ester hydrolysis is saponification (formation of soap). It is the hydrolysis of a triglyceride (fat) with an aqueous base such as sodium hydroxide (NaOH). During the process, glycerol is formed, and the fatty acids react with the base, converting them to salts. These salts are called soaps ...
Alkaline hydrolysis of esters is also known as saponification. A base such as sodium hydroxide is required in stochiometric amounts. Unlike acid-catalyzed ester hydrolysis, it is not an equilibrium reaction and proceeds to completion.
1920 – John B. Watson and Rosalie Rayner conduct the Little Albert experiment. 1928 – Griffith's experiment shows that living cells can be transformed via a transforming principle, later discovered to be DNA. 1934 – Enrico Fermi splits the atom. 1935 – Lady tasting tea experiment by Ronald A. Fisher, foundational in statistical ...
Fischer remained with Baeyer in Strassburg as an independent research student. In the fall of 1874, he was appointed assistant of the organic laboratory. There in 1875, he discovered and named hydrazines, including unsymmetrical dimethylhydrazine, which became important much later during the Space Race, and phenylhydrazine. [2]
They are used in soaps, medicines (e.g. drug adjuvants), fire extinguishers, dietary supplements, steroid synthesis, and in carbonated beverages (for example, being responsible for maintaining the head on root beer). Saponins are both water and fat soluble, which gives them their useful soap properties.
An image from John Dalton's A New System of Chemical Philosophy, the first modern explanation of atomic theory.. This timeline of chemistry lists important works, discoveries, ideas, inventions, and experiments that significantly changed humanity's understanding of the modern science known as chemistry, defined as the scientific study of the composition of matter and of its interactions.