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Alkali, or alkaline, soils are clay soils with high pH (greater than 8.5), a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate , which causes the soil to swell ...
Soils with higher buffering capacity require a greater amount of lime to achieve an equivalent change in pH. [67] The buffering of soil pH is often directly related to the quantity of aluminium in soil solution and taking up exchange sites as part of the cation exchange capacity. This aluminium can be measured in a soil test in which it is ...
A common approach is to change the soil acidity/soil pH because the pathogen prefers alkaline soils. A recommended method to decrease soil pH is through the application of ammonium sulfate or ammonium phosphate fertilizer at around 4.5 kg (10 lb) per 9.3 m 2 (100 sq ft).
Effect of soil pH on cation-exchange capacity. The amount of negative charge from deprotonation of clay hydroxy groups or organic matter depends on the pH of the surrounding solution. Increasing the pH (i.e. decreasing the concentration of H + cations) increases this variable charge, and therefore also increases the cation-exchange capacity.
Soil acidification is the buildup of hydrogen cations, which reduces the soil pH. Chemically, this happens when a proton donor gets added to the soil. The donor can be an acid , such as nitric acid , sulfuric acid , or carbonic acid .
The lower the pH, the higher the concentration of bicarbonate will be. This shows how a lower pH can lead to higher alkalinity if the amount of bicarbonate produced is greater than the amount of H + remaining after the reaction. This is the case since the amount of acid in the rainwater is low.
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The soil's pH also has a strong effect on the amount of volatilization. Specifically, highly alkaline soils (pH~8.2 or higher) have proven to increase urea hydrolysis. One study has shown complete hydrolysis of urea within two days of application on such soils. In acidic soils (pH 5.2) the urea took twice as long to hydrolyze. [7]