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Case-hardening or carburization is the process of introducing carbon to the surface of a low-carbon iron, or more commonly a low-carbon steel object, in order to harden the surface. Iron which has a carbon content greater than ~0.02% is known as steel .
The first air-hardening-grade tool steel was mushet steel, which was known as air-hardening steel at the time. Modern air-hardening steels are characterized by low distortion during heat treatment because of their high-chromium content.
S1, a medium-carbon shock-resisting steel tool steel which combines moderate hardness with good impact toughness. Carbon content 0.40 - 0.55%. [11] W1, a water hardening tool steel. High carbon content. W2, a tool steel that holds its edge quite well but is not very tough.
Examples of easily nitridable steels include the SAE 4100, 4300, 5100, 6100, 8600, 8700, 9300 and 9800 series, UK aircraft quality steel grades BS 4S 106, BS 3S 132, 905M39 (EN41B), stainless steels, some tool steels (H13 and P20 for example) and certain cast irons. Ideally, steels for nitriding should be in the hardened and tempered condition ...
Frequently, the term "hardening" is associated with tempered steel. Both processes are used hand in hand when hardening steel. The two part process begins with hardening the steel so that it becomes hard and does not wear over time. However, very often, this process leaves the steel very brittle and susceptible to breaking during use.
Very hard steel (e.g. chisels, quality knife blades): HRC 55–66 (Hardened High Speed Carbon and Tool Steels such as M2, W2, O1, CPM-M4, and D2, as well as many of the newer powder metallurgy Stainless Steels such as CPM-S30V, CPM-154, ZDP-189. There are alloys that hold a HRC upwards 68-70, such as the Hitachi developed HAP72.
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