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A Piper diagram is a graphical representation of the chemistry of a water sample or samples. The cations and anions are shown by separate ternary plots. The apexes of the cation plot are calcium, magnesium and sodium plus potassium cations. The apexes of the anion plot are sulfate, chloride and carbonate plus hydrogen carbonate anions.
Cations are positively (+) charged ions while anions are negatively (−) charged. This can be remembered with the help of the following mnemonics. Cats have paws ⇔ Cations are pawsitive. [23] Ca+ion: The letter t in cation looks like a + (plus) sign. [24] An anion is a negative ion. (An egative ion ⇒ Anion). [25]
Cations are plotted in milliequivalents per liter on the left side of the zero axis, one to each horizontal axis, and anions are plotted on the right side. Stiff patterns are useful in making a rapid visual comparison between water from different sources. An alternative to the Stiff diagram is the Maucha diagram.
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M (H 2 O) n] z+. The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table. Lanthanide and actinide aqua ions have higher solvation numbers ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In table salt (NaCl, also known as sodium chloride) the sodium ion (positively charged) is the counterion for the chloride ion (negatively charged) and vice versa. A counterion will be more commonly referred to as an anion or a cation, depending on whether it is negatively or positively charged. Thus, the counterion to an anion will be a cation ...