Search results
Results From The WOW.Com Content Network
Copper–chlorine cycle. The copper – chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius. [1]
The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium (II) chloride and copper (II) chloride as the catalyst. [1] This chemical reaction was one of the first homogeneous catalysis with organopalladium chemistry ...
Oxychlorination. In chemistry, oxychlorination is a process for generating the equivalent of chlorine gas (Cl 2) from hydrogen chloride and oxygen. [1] This process is attractive industrially because hydrogen chloride is less expensive than chlorine. [2]
Copper (II) chloride is used as a catalyst in a variety of processes that produce chlorine by oxychlorination. The Deacon process takes place at about 400 to 450 °C in the presence of a copper chloride: [8] 4 HCl + O2 → 2 Cl2 + 2 H2O. Copper (II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloromethane.
The reaction takes place at about 400 to 450 °C in the presence of a variety of catalysts, including copper chloride (CuCl 2). Three companies developed commercial processes for producing chlorine based on the Deacon reaction: [1] The Kel-Chlor process developed by the M. W. Kellogg Company, which utilizes nitrosylsulfuric acid.
At 298 K (25 °C), the chlorine-oxygen distances in each chlorate ion are 1.498, 1.488 and 1.468 Å, with the longest being the oxygen next to copper. The ∠O-Cu-O (angle subtended at copper by oxygen atoms) is 105.2°, 108.3°, and 106.8°. At lower temperatures (233 K, −40 °C), the water molecules and copper-chlorate distance shrink. [4]
In the above reaction, zinc metal displaces the copper(II) ion from the copper sulfate solution, thus liberating free copper metal. The reaction is spontaneous and releases 213 kJ per 65 g of zinc. The ionic equation for this reaction is: Zn + Cu 2+ → Zn 2+ + Cu. As two half-reactions, it is seen that the zinc is oxidized: Zn → Zn 2+ + 2 e −
In the area around a pressurized water reactor or boiling water reactor during normal operation, a significant amount of radiation is produced due to the fast neutron activation of coolant water oxygen via a (n,p) reaction. The activated oxygen-16 nucleus emits a proton (hydrogen nucleus), and transmutes to nitrogen-16, which has a very short ...