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Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. [1] [2] [3] The angles between bonds that an atom forms depend only weakly on the rest of molecule, i.e. they can be understood as approximately local and hence transferable properties.
In Euclidean geometry, an angle or plane angle is the figure formed by two rays, called the sides of the angle, sharing a common endpoint, called the vertex of the angle. [1] Two intersecting curves may also define an angle, which is the angle of the rays lying tangent to the respective curves at their point of intersection.
Another example is O(SiH 3) 2 with an Si–O–Si angle of 144.1°, which compares to the angles in Cl 2 O (110.9°), (CH 3) 2 O (111.7°), and N(CH 3) 3 (110.9°). [24] Gillespie and Robinson rationalize the Si–O–Si bond angle based on the observed ability of a ligand's lone pair to most greatly repel other electron pairs when the ligand ...
This angle may be calculated from the dot product of the two vectors, defined as a ⋅ b = ‖ a ‖ ‖ b ‖ cos θ where ‖ a ‖ denotes the length of vector a. As shown in the diagram, the dot product here is –1 and the length of each vector is √ 3, so that cos θ = – 1 / 3 and the tetrahedral bond angle θ = arccos ...
In stereochemistry, a torsion angle is defined as a particular example of a dihedral angle, describing the geometric relation of two parts of a molecule joined by a chemical bond. [ 4 ] [ 5 ] Every set of three non-colinear atoms of a molecule defines a half-plane.
In geometry, an inscribed angle is the angle formed in the interior of a circle when two chords intersect on the circle. It can also be defined as the angle subtended at a point on the circle by two given points on the circle. Equivalently, an inscribed angle is defined by two chords of the circle sharing an endpoint.
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Its vertex–center–vertex angle—the angle between lines from the tetrahedron center to any two vertices—is = (), denoted the tetrahedral angle. [9] It is the angle between Plateau borders at a vertex. Its value in radians is the length of the circular arc on the unit sphere resulting from centrally projecting one edge of the ...