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The IUPAC definition [1] of relative atomic mass is: An atomic weight (relative atomic mass) of an element from a specified source is the ratio of the average mass per atom of the element to 1/12 of the mass of an atom of 12 C. The definition deliberately specifies "An atomic weight ...", as an element will have different relative atomic masses ...
Thus, the atomic mass of a carbon-12 atom is 12 Da by definition, but the relative isotopic mass of a carbon-12 atom is simply 12. The sum of relative isotopic masses of all atoms in a molecule is the relative molecular mass. The atomic mass of an isotope and the relative isotopic mass refers to a certain specific isotope of an element.
Definition Name Symbol relative atomic mass: A r: Ratio of the average mass per atom of an element to 1/12 of the mass of an atom of the nuclide 12 C one 1 Formerly called atomic/molecular weight. Example: A r (Cl) = 35.453. Both quantities depend on the nuclidic composition. relative molecular mass: M r
Atomic weight and relative atomic mass are synonyms. The standard atomic weight is a special value of the relative atomic mass. It is defined as the "recommended values" of relative atomic masses of sources in the local environment of the Earth's crust and atmosphere as determined by the IUPAC Commission on Atomic Weights and Isotopic ...
The molar mass constant, usually denoted by M u, is a physical constant defined as one twelfth of the molar mass of carbon-12: M u = M(12 C)/12. [1] The molar mass of an element or compound is its relative atomic mass (atomic weight) or relative molecular mass (molecular weight or formula weight) multiplied by the molar mass constant.
A r (e) is a directly measured quantity, the relative atomic mass of the electron. m u is defined in terms of A r (e), and not the other way round, and so the name "electron mass in atomic mass units" for A r (e) involves a circular definition (at least in terms of practical measurements).
The mass number gives an estimate of the isotopic mass measured in atomic mass units (u). For 12 C, the isotopic mass is exactly 12, since the atomic mass unit is defined as 1/12 of the mass of 12 C. For other isotopes, the isotopic mass is usually within 0.1 u of the mass number.
The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet, and even from place to place on the Earth, but remains relatively constant in time (on a short-term scale).