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For example, the relative isotopic mass of a carbon-12 atom is exactly 12. For comparison, the atomic mass of a carbon-12 atom is exactly 12 daltons. Alternately, the atomic mass of a carbon-12 atom may be expressed in any other mass units: for example, the atomic mass of a carbon-12 atom is 1.992 646 882 70 (62) × 10 −26 kg.
The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115. Mass excess should not be confused with mass defect which is the difference between the mass of an atom and its constituent particles (namely protons, neutrons and electrons). There are two reasons for mass ...
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a body, until the discovery of the atom and particle physics. It was found that different atoms and different elementary particles, theoretically with the same amount of matter, have nonetheless different masses.
Nominal mass is a term used in high level mass spectrometric discussions, it can be calculated using the mass number of the most abundant isotope of each atom, without regard for the mass defect. For example, when calculating the nominal mass of a molecule of nitrogen (N 2) and ethylene (C 2 H 4) it comes out as. N 2 (2*14)= 28 Da C 2 H 4
In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [12] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [13]
The mass defect used in nuclear physics is different from its use in mass spectrometry. In nuclear physics, the mass defect is the difference in the mass of a composite particle and the sum of the masses of its component parts. In mass spectrometry the mass defect is defined as the difference between the exact mass and the nearest integer mass.
It can be converted into a measure of mass (with dimension M) by multiplying it with the dalton, also known as the atomic mass constant. Among various variants of the notion of atomic weight (A r, also known as relative atomic mass) used by scientists, the standard atomic weight (A r °) is the most common and practical.
The molar mass constant, usually denoted by M u, is a physical constant defined as one twelfth of the molar mass of carbon-12: M u = M(12 C)/12. [1] The molar mass of an element or compound is its relative atomic mass (atomic weight) or relative molecular mass (molecular weight or formula weight) multiplied by the molar mass constant.